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Directions
Preheat oven to 350 degrees F.
Use 1 tablespoon of butter to grease 3 (9-inch) cake pans. Line the bottom of each pan with a parchment paper round.
Combine cocoa and chocolate in medium bowl. Pour boiling water over the chocolate mixture and whisk until smooth; reserve. Sift together the flours, baking soda, and salt into a medium bowl; reserve.
Place the 3/4 pound butter in large bowl and beat with electric mixer at medium-high until creamy, about 1 minute. Add dark brown and granulated sugars and beat on high until light and fluffy, about 3 minutes. Stop mixer and scrape down bowl with rubber spatula. Add the eggs, 1 at a time, beating 30 seconds on medium-high after each addition. Reduce speed to medium and add sour cream and vanilla. Beat until combined. Stop mixer and scrape down bowl. With mixer on low add about 1/3 of flour mixture, followed by about 1/2 of chocolate mixture. Repeat ending with flour mixture, beating until just combined. Stop mixer and scrape down sides of bowl. Stir gently to thoroughly combine. Divide batter evenly among cake pans and smooth with spatula. Bake until skewer inserted in center
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