Jumbo Maple-Pecan Scone

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3/4 cup buttermilk, plus more for brushing

1 teaspoon vanilla extract

2 1/4 cups all-purpose flour, plus more for dusting

1/4 cup granulated sugar

1 tablespoon baking powder

1/2 teaspoon baking soda

1/2 teaspoon grated orange zest

1/4 teaspoon freshly grated nutmeg

1/2 teaspoon ground cinnamon

1/2 teaspoon kosher salt, plus a pinch

12 tablespoons (1 1/2 sticks) unsalted butter, cut into small pieces and chilled

1/2 cup pecan pieces, toasted

1/4 cup confectioners' sugar

3 tablespoons maple syrup