Heat an outdoor grill or grill pan to medium heat. Stir the syrup and hot sauce, if you'd like these extra spicy, in a small bowl. Cut each slice of ham into strips a little wider than each pineapple chunk, about 1½ inches. Wrap each strip around a pineapple chunk, top with a jalapeno slice, and skewer. Grill, turning once, until grill marks appear, about 4 minutes. Lightly brush with the syrup mixture and grill until the honey caramelizes onto the skewers, about 2 minutes. Use a spatula to remove from the grill to avoid tearing the ham. Serve hot, warm, or at room temperature.
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