In a large pitcher, combine the vodka, vegetable juice, Worcestershire sauce, horseradish, and jalapeno juice; mix thoroughly. For each cocktail, rub a lemon wedge around the rim of a 12-ounce high-ball glass and dip the glass upside-down into the celery salt, coating the rim with salt. Fill the glass with ice and pour the drink mixture over top. Garnish with a lemon wedge and a whole chili pepper. Repeat for each cocktail and serve immediately.