Butter a 9-inch square baking dish. Preheat the oven to 400 degrees F.
In a saucepan, melt the butter until just bubbling. Remove from the heat and whisk in the sugars until combined.
Add the bittersweet chocolate, then stir to melt, 2 to 3 minutes. Add the egg and vanilla, then mix until well combined. Add the flour, cocoa powder and salt, then fold until well mixed. Transfer to the prepared baking dish.
Bake until just set in the middle, 18 to 20 minutes. Let cool completely, about 20 minutes.
Cut and transfer the brownies to a food processor; alternately, you can use a hand mixer. Add the softened cream cheese and process until smooth.
Using a mounded 1-tablespoon scoop, remove golf ball-size portions of the mixture and roll so that they are perfectly round. Place on a sheet tray lined with parchment paper. Place the tray in the freezer for 10 minutes to firm up.
Melt the dark baking chocolate over a double boiler until smooth.
Using a fork, dip the truffles in the chocolate, coating them completely. Tap the fork on the side of the bowl to remove any excess chocolate. Place on a wax paper-lined baking sheet immediately, then sprinkle with the pistachios.
Return to the freezer to let the chocolate harden for 5 to 10 minutes.
Serve or transfer to an airtight container. The truffles can be stored at room temperature for a couple of days or in the fridge for up to 2 weeks.
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