Mix together the cream cheese and chives in a bowl. Cut the pimentos into small pieces.
Spread a thin layer of the cream cheese mixture onto a salami slice; fold in half, then half again to form a wedge shape. Thread 2 pieces of pimento onto toothpicks and use to secure the roll-up. Repeat for the remaining salami slices.
Slice the roll-ups in half and serve on a platter.