Shake the chocolate liqueur, creme de cacoa, and vanilla-flavored vodka over ice.
Place chocolate syrup in a shallow bowl or plate. In a separate plate or bowl, add the graham crackers. Rim a glass with chocolate syrup and then press in graham crackers.
Strain and pour in the cocktail mixture, then cover with marshmallow fluff and carefully brulee the fluff.
Series: Drinks with Alie and Georgia Episode: S'Mores Cocktail (Ep. 22: Part 1)
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