Couscous with Orange and Almonds

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2 cups instant couscous

2 cups boiling water

1 teaspoon salt, plus more for seasoning

1 teaspoon finely grated orange zest

2 tablespoons fresh orange juice

2 tablespoons red wine vinegar

1/4 cup extra-virgin olive oil

1/2 medium onion, thinly sliced

1 orange, peeled, segmented and diced

3 tablespoons finely chopped fresh mint leaves

3 tablespoons finely chopped fresh flat-leaf parsley

1 head radicchio, shredded

Freshly ground black pepper

Toasted slivered almonds